This study strives to perform a pilot collection assessment study with the political science collection in a university library. Employing the basic list-checking analysis method, the study scrutinized the collection statistics and the circulation statistics, and check the current library holdings with a standard list which was composed of cited works extracted from course syllabi, theses, dissertations and faculty research papers. Although the study is a pilot case study that a particular model was applied to a collection in the field of political science, the result and procedures of the assessment will provide some implications regarding collection assessment in university libraries.