The study was carried out for the purpose of identifying implications that should be considered in educating DDC through online within Library and Information Science curriculum. Followed by operating a NCS-based educational course utilizing printed matter and web version of DDC, two tests and survey were conducted to analyze learning outcomes, satisfaction, and preferences by learning tools. The result showed that differences in educational medium do not correlate to educational performance significantly. However, during the learning process, the mainly used medium affects the usefulness, preference and future utilization of the medium. Based on the research results, when designing DDC education using WebDewey in the future, compared to the printed version, relative understanding for utilizing the structure and its items of DDC classification, built numbers and education for understanding Web Dewey interface and function are required.