- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
2002, v.15 no.6, pp.550-555
(2002). The Study on the Mechanism for Oxidation Reaction of Boratabenzne by Cyclic Voltammetry. Analytical Science and Technology, 15(6), 550-555.
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Abstract
The oxidation mechanism of boratabenzene was studied. As a model compound the ferrocene analogue (<TEX>${\eta}^6$</TEX>-1-Methylboratabenzene)(<TEX>${\eta}^5$</TEX>-Pentamethylcyclopentadiennyl)iron 3 was chosen. The complex underwent irreversible oxidation in the presence of ortho proton on the ring and a methyl group on the boron atom in methanol medium. Chemical oxidations with <TEX>$Hg(OAc)_2$</TEX>, <TEX>$HgSO_4$</TEX>, <TEX>$Cu(OH)_2$</TEX>, <TEX>$AgCF_3SO_3$</TEX> or <TEX>$FeCl_3$</TEX> in MeOH gave, via a transition state [3], at first the derivates 6 and 7, which were converted to each 8 and 9.
- keywords
- Cyclic Voltammetry, Reaction mechanism, Boratabenzene, Oxidation, Complex
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