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  • 한국과학기술정보연구원(KISTI) 서울분원 대회의실(별관 3층)
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  • P-ISSN1225-0163
  • E-ISSN2288-8985
  • SCOPUS, ESCI, KCI

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  • P-ISSN 1225-0163
  • E-ISSN 2288-8985

논문 상세

    무등산 숲과 도심에서 휘발성유기화합물질의 분포 특성

    Distribution characteristics on volatile organic compounds at the forest of Mt. mudeung and downtown

    분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
    2015, v.28 no.3, pp.246-254
    https://doi.org/10.5806/AST.2015.28.3.246
    이대행 (광주광역시보건환경연구원)
    박강수 (광주광역시보건환경연구원)
    이세행 (광주광역시보건환경연구원)
    송형명 (광주광역시보건환경연구원)
    이기원 (광주광역시보건환경연구원)
    정희윤 (광주광역시보건환경연구원)
    서광엽 (광주광역시보건환경연구원)
    조영관 (광주광역시보건환경연구원)
    김은선 (광주광역시보건환경연구원)
    • 다운로드 수
    • 조회수

    초록

    무등산 탐방로 8개 지점과 도심 1개 지점에서 2013~2014년에 자연 기원 휘발성유기화합물질(BVOCs)과 인위적인 휘발성유기화합물질 (AVOCs)의 분포특성을 GC-MSD를 사용하여 조사하였다. 자연기원 휘발성유기화합물인 테르펜 발생량은 편백숲인 PA 지점이 821 pptv으로 가장 높았고, WH 지점이 785 pptv, NZ 지점이 679 pptv, DJ 지점이 513 pptv, JB 지점이 476 pptv, SS 지점이 464 pptv 순으로 조사되었다. 테르펜은 지점별로 11~15 종이 검출되었는데, 5월에 PA 지점에서는 α-pinene이 20% 로 가장 높고, coumarin, sabinene, phellandrene, myrcene, borneol, eucalyptol, β-pinene, cymene, δ- limonene, γ-terpinene, camphor, camphene, mentol 순이었다. 인위적인 휘발성유기화합물질(AVOCs)은5~7월에 숲 8개 지점에서 0.74~2.52 ppbv 이었고, 도심(JW 지점)에서는 3.14 ppbv로 나타나 도심/산림비율은 1.9~4.0로 도심지역이 높았다. JW 지점에서 벤젠과 톨루엔만 합한 농도는 평균 2.37 ppbv로AVOCs 10항목 전체의 75%를 차지했다. 6월 중 AVOCs 종별 분포조사 결과, 숲인 DJ 지점에서 toluene 이 44.1%로 가장 많았고, 도심인 JW 지점에서도 toluene이 53.1%로 가장 많았다. 또한, 숲에서 AVOCs 와 BVOCs 농도의 상관성 분석 결과, 양의 상관계수가 0.328이나 유의인자(p)는 0.184로서 통계적으로유의하지 않는 것으로 나타나 숲에서의 AVOCs는 도심에서 영향을 받은 것으로 추정된다.

    keywords
    biogenic volatile organic compounds, anthropogenic volatile organic compounds, terpene, forest, downtown

    Abstract

    From 2013 to 2014, volatile organic compounds (VOCs) were analyzed to determine biogenic volatile organic compounds (BVOCs) and anthropogenic volatile organic compounds (AVOCs) at eight sites in Mt. Mudeung and one site in downtown, by using a GC/Mass-ATD (automatic thermal desorber). The concentration of terpene noted as biogenic volatile organic compounds at Pungamjeong (PA), in a forest of Chamaecyparis obtusa, was 821 pptv, which was the highest among the eight sites. This value was followed by Wonhyogyegok (WH: 785 pptv), Norritzae (NZ, coniferous forest: 679 pptv), Dongjeokgol (DJ, mixed species forest: 513 pptv), Jangbuljae (JB, Abies koreana: 476 pptv), and Seinbongsamgerri (SS, pine trees: 464 pptv). 11~15 species of terpene was detected in the forest depending on the site. At PA in May, α-pinene showed the highest value, occupied 20% of terpene followed by coumarin, sabinene, phellandrene, myrcene, borneol, eucalyptol, β-pinene, cymene, δ- limonene, γ-terpinene, camphor, camphene, and mentol in the order. The mean concentrations of AVOCs were 0.74~2.52 ppbv in the forests and 3.14 ppbv in the downtown area. From May to July, the AVOCs ratios of the downtown to each forest were 1.9~4.0. Among 10 species of AVOCs, the sum of toluene and benzene was 2.34 ppbv and occupied 75%. In June, the ratios of toluene were 44.1% at DJ site and 53.1% at JW site (downtown). The BVOCs showed a positive correlation with the AVOCs at the forest sites (r = 0.328), which was statistically insignificant (p = 0.184).

    keywords
    biogenic volatile organic compounds, anthropogenic volatile organic compounds, terpene, forest, downtown


    참고문헌

    1

    1. J. C. Kim, J. H. Hong, C. H. Gang, W. Y. Sun, K. J. Kim and J. H. Lim, J. Kor. Soc. for Atmos. Environ., 20(2), 175-183 (2004).

    2

    2. D. Harrison, M. C. Hunter, A. C. Lewis, P. W. Seakins, T. W. Nunes and C. A. Pio, J. Kor. Soc. for Atmos. Environ., 35, 4687-4698 (2001).

    3

    3. M. Staudt, N. Bertin, U. Hansen, G. Seufert, P. Ciccioli, P. Foster, B. Frenxel, J. L. Fugit and L. Torres, J. Kor. Soc. for Atmos. Environ., 31, 145-156 (1997).

    4

    4. J. C. Kim, J. Kor. Soc. for Atmos. Environ., 35, 3279-3292 (2001).

    5

    5. J. C. Kim, J. Kor. Soc. for Atmos. Environ., 17(E2), 61-70 (2001).

    6

    6. K. W. Kim, J. Kor. Soc. for Plant Human Environ., 9(4), 111-123 (2006).

    7

    7. M. J. Kim, Y. H. Choi, J. W. Lee, B. J. Park and Y. J. Jeon, J. Kor. Soc. of Environ. and Ecology proceeding thesis, 97-101 (2007).

    8

    8. W. S. Shin and S. G. Kim, J. Kor. Forest Soc., 96(2), 203-207 (2007).

    9

    9. Korea forest Research Institute, ‘Development of Health Healing Program using Forest’, Korea Forest Service (2011).

    10

    10. Jeonnam Institute of Health and Environment, Research Seminar for Health and Environment, 65-81 (2008).

    11

    11. N. S. Kong, H. S. Choi, J. H. Byun, J. S. Park, H. Y. Lee, The Report of Health and Environment Research Institute of Gyungnam, 153-169 (2010).

    12

    12. D. H. Lee, M. H. Kim, H. J. Seo, G. W. Min, S. H. Kim, G. Y. Seo, W. S. Jeong, Y. J. Kang, K. W. An, K. J. Baik, Y. W. Moon and E. S. Kim, J. Environ. Sci., 21(10), 1221-1234 (2012).

    13

    13. D. H. Lee, M. H. Kim, O. H. Park, K. S. Park, S. S. An, H. J. Seo, S. H. Jin, W. S. Jeong, Y. J. Kang, K. W. An and E. S. Kim, J. Environ. Health Sci., 39(3), 211-222 (2013).

    14

    14. M. S. Her, ‘Characteristics of VOCs’ Behavior in air during High Concentration Ozone in Summer’, Master Dissertation, Seoul National University, Seoul (2007).

    15

    15. G. Y. Her, ‘Long-term Analysis of Ozone Concentration on the Ground of Seoul Area using KZ Filter’, Master Dissertation, Seoul National University, Seoul (2000).

    16

    16. H. J. Jeong, ‘A Study on the Development of Ozone Forecast System and the Variation of Ozone Concentration by Photochemical Reaction at the air of Daejeon Area’, Ph. D. Dissertation, Wongwang University, Jeonju, Jeollabukdo (2001).

    17

    17. J. H. Lim, ‘A Comparison Study on Emission Rates of Natural VOC from Coniferous Trees’, Master Dissertation, Gunguk University, Seoul (2004).

    18

    18. B. S. Lee, A Study on Natural Season of Korea, Geography, 14(2), 1-11 (1979).

    19

    19. Ministry of Environment, Indoor Air Pollution Test Method, 17-22 (2010).

    20

    20. Ministry of Environment, Air Pollution Test Method, 862-863 (2008).

    21

    21. A. Rivoal, C. Fernandez, A. V. Lavoir, R. Olivier, C. Lecareux, S. Greff, P. Roche and B. Vila, Chemosphere, 78, 942-949 (2010).

    22

    22. D. Y. Ji, S. Y. Kim and J. S. Han. J. Kor. Soc. for Atmos. Environ., 18(6), 515-525 (2002).

    23

    23. H. C. Kim and K. H. Lee, J. Kor. Soc. for Environ. Sci., 19(5), 627-637 (2010).

    24

    24. National Institute of Environmental Research, Final Report (2012), Korea University, 1-41, Republic of Korea.

    25

    25. G. J. Kim, J. C. Kim and J. H. Lim, J. Kor. Soc. for Environ. Analysis, 8(3), 132-136 (2005).

    26

    26. H. Y. Kang, ‘The Secret of Phytoncide’, History-Net Press, 66-68 (2003).

    27

    27. D. H. Lee, S. S. An, H. M. Song, O. H. Park, K. S. Park, G. Y. Seo, Y. G. Cho and E. S. Kim, Environ. Health Sci., 40(3), 204-214 (2014).

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