- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Determination of Li by Isotope Dilution Inductively Coupled Plasma Mass Spectrometry
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.427-434
Park,
C. J., &
Chung,
B.
S.
(1995). Determination of Li by Isotope Dilution Inductively Coupled Plasma Mass Spectrometry. , 8(4), 427-434.
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Abstract
Inductively coupled plasma mass spectrometry combined with the isotope dilution method is used for the determination of lithium. The isotope dilution method is based on the addition of a known amount of enriched isotope (spike) to a sample. The analyte concentration is obtained by measuring the altered isotope ratio. The spike solution is calibrated through so called reverse isotope dilution with a primary standard. The spike calibration is an important step to minimize error in the determined concentration. It has been found essential to add spike to a sample and the primary standard so that the two isotope ratios should be as dose as possible. Since lithium is neither corrosive nor toxic, lithium is used as a chemical tracer in the nuclear power plants to measure feedwater flow rate. 99.9% <TEX>$^7Li$</TEX> was injected into a feedwater line of an experimental system and sample were taken downstream to be spiked with 95% <TEX>$^6Li$</TEX> for the isotope dilution measurements. Effects of uncertainties in the spike enrichment and isotope ratio measurement error at various spike-to-sample ratios are presented together with the flow rate measurement results in comparison with a vortex flow meter.
- keywords
- ICP-MS, isotope dilution, lithium, chemical tracer, flow rate
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