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Some Peroxysterols and Ceramides from "Phellinus ribis", a Korean Wild Mushroom
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.901-906
Moon,
D., Hwang,
K., Choi,
K., Choi,
D., Kim,
C., Kim,
J., Lee,
Y., &
Zee,
O.
(1995). Some Peroxysterols and Ceramides from "Phellinus ribis", a Korean Wild Mushroom. Analytical Science and Technology, 8(4), 901-906.
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Abstract
Studies on the chemical constituents from a Korean wild mushroom, Phellinus ribis, were carried out. A triterpenoid, two peroxysterols, and a chlorobenzene compound were isolated from the hexane soluble fraction of the methanol extract of dried fruiting bodies of the basidomycetes. Those compounds identifed were 3-hydroxy-20(29)-lupen-28-oic acid (betulinic acid), 5,8-epidioxyergosta-6,22-dien-3-ol(ergosterol peroxide), 5,8-epidioxyergosta-6,9(11),22-trien-3-ol (dehydroperoxyergosterol), and 1,2,4,5-tetrachloro-3,6-dimethoxybenzene. Structural studies were carried out on molecular species of a ceramide and cerebroside isolated from the chloroform soluble fraction of the methanol extract. For ceramide, the major component fatty acids were a-hydroxy fatty acid isomers of <TEX>$C_{22:00}{\sim}C_{25:00};$</TEX> the predominant long-chain bases were trihydroxy sphinganine of <TEX>$C_{17}{\sim}C_{18}$</TEX>. The structure of a cerebroside containing mono-sugar was assumed that the long-chain base was <TEX>$C_{19:2}$</TEX> sphingadienine; the major fatty acids were <TEX>$C_{16}{\sim}C_{15}$</TEX> <TEX>${\alpha}$</TEX>-hydroxy fatty acid isomers.
- keywords
- Phellinus ribis, triterpenoids, peroxysterols, chlorobenzene, ceramides, cerebrosides
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