Electrocatalytic Reduction of Dioxygen at Schiff base Co(II) Complexes supported Glassy Carbon Electrode in various pH Solution
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.617-622
Park, Kyoung-Hee
Rim, Chae-Pyeong
Chjo, Ki-Hyung
Jeon, Seungwon
Choi, Yong-Kook
Park,
K., Rim,
C., Chjo,
K., Jeon,
S., &
Choi,
Y.
(1995). Electrocatalytic Reduction of Dioxygen at Schiff base Co(II) Complexes supported Glassy Carbon Electrode in various pH Solution. , 8(4), 617-622.
Abstract
Electrocatalytic reduction of dioxygen has been investigated by cyclic voltammetry at glassy carbon electrode modified with new Co(II)-Schiff base complexes in aqueous solutions of various pH. The reduction potentials of dioxygen at chemically adsorbed electrodes show the dependence of pH between pH 4 and 14. The catalytic effect is large and the reaction occurs via two or four electron transfer in various pH solution.
- keywords
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Electrocatalytic dioxygen reduction,
Co(II)-Schiff base complexes,
Modified electrodes,
Catalytic effect,
Various pH solution,
Cyclic voltammetry