- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
Article Detail
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Electrochemical Study of Poly(aniline N-alkylsulfonate)s
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.631-636
Kim,
E., &
Rhee,
S.
B.
(1995). Electrochemical Study of Poly(aniline N-alkylsulfonate)s. , 8(4), 631-636.
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Abstract
Electrochemical properties of self-dopable poly(aniline N-butylsulfonate)s in various acidic medium were investigated by spectroelectrochemical techniques. Cyclic voltammetric study showed more than two reversible process of one electron transfer, the potential and peak intensity of which were dependent on the acid concentration and dopant ion. Spectroscopic study at different oxidation level indicated that the electrochromic switching of the poly(aniline N-alkylsulfonate)s film involves structural changes from benzenoid ring to quinoid ring. Spectrocyclic voltammetry together with impedance spectra of the PANBUS film in 0.1 M <TEX>$LiClO_4$</TEX> solution of acetonitrile containing 0.46 M of perchloric acid showed two types of highly conductive states at the intermediate oxidation levels, which can be related to the metallic polaron states doped by two different process.
- keywords
- poly(aniline N-alkylsulfonate)s, poly(aniline N-butylsulfonate)s, doping mechanism, spectroelectrochemistry, impedance study
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