- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Determination of Stability Constants Using Electrochemical Methods for the Complex Formation of Platinum and Palladium with Polyelectrolytes
Analytical Science and Technology / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.691-698
Park,
J. S., &
Chung,
K.
S.
(1995). Determination of Stability Constants Using Electrochemical Methods for the Complex Formation of Platinum and Palladium with Polyelectrolytes. , 8(4), 691-698.
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Abstract
The complexation of platinum and palladium with synthetic polyelectrolytes was studied. The successive and overall stability constants of Pd(II) with PEI and 2PVP were obtained by potentiometric titration. Because of the slow equilibrium time, the potentiometric titrations were performed using the home-made automatic titrator in order to analyze the complexations according to the modified Bjerrum method. The complex formation constant of Pt(IV) with 2PVP, measured by differential pulse polarography, was calculated from the peak currents that were obtained in non-complexing media and in solution containing 2PVP.
- keywords
- Polyelectrolyte, Palladum, Platinum, Potentiometric Titration, Differential Pulse Polarography
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