- P-ISSN 1225-0163
- E-ISSN 2288-8985
- P-ISSN1225-0163
- E-ISSN2288-8985
- SCOPUS, ESCI, KCI
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Metal Ion Selectivity of Surface Templated Resins Carrying Phosphate Groups
분석과학 / Analytical Science and Technology, (P)1225-0163; (E)2288-8985
1995, v.8 no.4, pp.529-534
Murata,
M., Maeda,
M., &
Takagi,
M.
(1995). . , 8(4), 529-534.
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Abstract
The metal ion selective resins were prepared by surface template polymerization using monooleyl phosphoric acid (1), oleyl methyl phosphoric acid (2) or oleyl ethyl phosphoric acid (3) as an amphiphilic host surfactant. The <TEX>$Cu^{2+}$</TEX>-imprinted resins prepared in the presence of <TEX>$Cu^{2+}$</TEX> adsorbed <TEX>$Cu^{2+}$</TEX> much more effectively than did their reference resins. On the other hand, the <TEX>$Cu^{2+}$</TEX>-imprinted resins showed much less binding ability to <TEX>$Zn^{2+}$</TEX>. The template-dependent selectivity should be ascribed to a favorable placement of the surface-anchored metallophilic groups for multidentate coordination to specific metal ion.
- keywords
- Surface template polymerization, ion exchange resin, phosphoric acid, divinylbenzene, selective metal ion adsorption
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